Cristiano Ronaldo was news just after the Barcelona v Real Madrid match ended, in which Los Blancos won 3-1 away to their rivals.
Madrid captain Ramos was substituted in last week's home defeat to Cadiz and missed the subsequent shock reverse against Shakhtar Donetsk in the Champions League as the Spanish champions crept towards a crisis ahead of their first meeting with Barca this season.
Barcelona coach Ronald Koeman, taking charge of his first El Clasico, made three changes as fit-again Jordi Alba returned while 17-year-old midfielder Pedri also come in.
At the start of the second half, Ramos headed wide from a corner before 17-year-old Fati nearly grabbed another goal after being picked out by Messi, but dragged his shot wide after cutting back inside.
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Ramos, making a record 45th appearance in the "Clasico" fixture, was awarded the spot-kick following a VAR review, after falling in the area when his shirt was tugged by Barcelona's Clement Lenglet as the pair contested a corner. Real Madrid go top of the table while Barcelona are down in 10th.
Neto saved from Vinicius Junior as Real pushed for a third, before at the other end Dembele sent a chip over the crossbar. "When you wear this badge you have to give everything in the 90 minutes, and we really put in a big effort today and deserved to get the win".
Zidane's men move two points clear of Real Sociedad, while Barcelona are 10th following a second straight LaLiga defeat.
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